![]() |
Evaluation Of Crushed Recycled Glass
as a Filtration Medium In Slow Sand Filtration
|
Report No. GL-95-4
Prepared for
Recycling Technology Assistance Partnership (ReTAP)
A program of the Clean Washington Center (CWC),
A division of the Pacific
Northwest Economic Region (PNWER)
2200 Alaskan Way, Suite 460
Seattle, Washington 98121
December, 1995
Prepared by
Gray & Osborne, Inc.
701 Dexter Avenue North,
Suite 200
Seattle, Washington 98109
This recycled
paper is recyclable
Copyright ©1995 by Clean Washington Center
LINKS
This report contains links to outside resources and
documents that are pertinent to the context of the information in this
report. The following list will take
you to the point in the report where you can use each link:
CWC (formerly the Clean Washington
Center)
Environmental Protection Agency
NIST Manufacturers’ Extension
Service
The Pacific Northwest Economic Region (PNWER)
A CWC report on the use of glass in swimming
pool filters
A CWC report on the use of glass in septic
treatment filters
A CWC report on the use of glass in water
well filters
EVALUATION OF CRUSHED
RECYCLED GLASS AS FILTRATION MEDIA IN SLOW RATE SAND FILTRATION
CONTENTS
1.0 PURPOSE OF STUDY............................................................. 1
2.0 BACKGROUND...................................................................... 2
2.1 Study
Location................................................................... 2
2.2 Description
of Existing Drinking Water System.................... 2
2.3 Regulatory
Mandate........................................................... 3
3.0 SLOW SAND FILTRATION
TESTS..................................... 4
3.1 Materials
and Apparatus..................................................... 5
3.2 Methods
of Operation........................................................ 8
4.0 TEST PARAMETERS AND
RESULTS.............................. 10
4.1 Turbidity........................................................................... 10
4.2 Rate of
Headloss Development......................................... 11
4.3 Bacteriological
Testing...................................................... 13
4.4 Temperature
and pH......................................................... 14
4.5 Disinfection
By-Products.................................................. 14
4.6 Metals
and VOCs............................................................ 16
4.7 Overall
Effectiveness of Filter Media................................. 16
4.8 Operational
Procedures and Full Scale Design
Considerations.................................................................. 18
5.0 CONCLUSIONS AND RECOMMENDATIONS............... 18
APPENDICES
Appendix A. Chemical
Analyses
Appendix B. System
Diagram
Turbidities
Head
Losses
Coliform
Removal Efficiencies
Appendix C. Trihalomethanes
1.0 PURPOSE OF STUDY
The purpose of
this study was to evaluate the feasibility of using crushed, recycled glass as
a filtration medium in slow sand filters. Slow sand filtration is also referred
to as slow rate filtration. Slow sand
filters are increasingly being used to treat drinking water in small
communities (typically less that 10,000 people) to meet state water quality
regulations. This is due primarily to
the low costs associated with constructing and maintaining slow sand
facilities. Because coagulants or other
methods of pretreatment generally are not used in slow sand filtration, slow
sand facilities are usually limited to relatively clean water sources with no
heavy seasonal algal blooms, and average turbidities below five turbidity
units.[1]
The City of Roslyn
was selected as a test site, and raw water samples were drawn upstream of the
City’s municipal water supply reservoir.
Raw water characteristics are summarized in Appendix A.
Sand is
typically the medium used in direct filtration systems of this type. Consequently, crushed, recycled glass was
evaluated concurrently with three other sand media during a pilot project
evaluation of slow rate filtration alternatives for the City of Roslyn. The pilot project was conducted to validate
the effectiveness of this treatment process for this water source and to
generate information to be used in optimizing the design of a full-scale
facility.
The evaluation
of the crushed, recycled glass was funded by the Recycling Technology
Assistance Partnership of the Clean Washington Center (ReTAP), the
Manufacturers’ Extension Partnership of the National Institute for Standards
and Technology (NIST MEP), and the Environmental Protection Agency.
Caution must be used when applying the conclusions of this pilot project to other water systems. The effectiveness of a filter medium and slow sand filtration treatment of drinking water are site specific such that each filter medium must be evaluated on a case-by-case basis.
It is not
expected that processed glass will find wide usage in slow sand filtration at
any time soon. A typical slow sand
filter contains 4000-7000 cubic feet of sand.
A facility may have two to six filters.
Therefore 10,000-40,000 cubic feet of filtration medium may be contained
at one facility. The full amount of
filtration medium is purchased for initial start-up, with smaller quantities
used for filter renewal on an ongoing basis.
It is not currently possible to purchase over 10,000 cubic feet of glass
processed to a relatively tight gradation at one time. In addition, it is probably not practical to
mix media between filters in a single installation because the difference in
specific gravity between glass and natural aggregate may result in variations
between the different media filters during
backflushing. In addition, if
the media were mixed in a single filter, it is likely that the difference in
specific gravity would cause the media to stratify over time, with the glass
rising to the top.
This study adds
to the body of knowledge on glass as a filtration medium. There may be a practical market niche for
glass processors in smaller scale single-pass or recirculating water filters.
2.0
BACKGROUND
The use of glass as a filtration medium, for recirculating water filters, water well
filtration, and waste water treatment,
has been investigated in other CWC reports.
2.1 STUDY
LOCATION
The City of
Roslyn is located in Kittitas County in the Cascade Mountain Range of
Washington. The City is located
approximately 3 miles north of Interstate 90 and approximately 85 miles east of
Seattle. The current population is
approximately 900 people.
2.2 DESCRIPTION
OF EXISTING DRINKING WATER SYSTEM
The source of
water for the City’s drinking water system is Domarie Creek. The system intake is located approximately
15 miles northwest of the City. A 12
inch, steel transmission line transports water by gravity to the City’s
concrete, open reservoir. The water is
treated by a positive pressure chlorination system prior to entering the 1.0
million gallon (MG) reservoir, from which water enters the distribution
system. The City is in the process of
installing slow sand filtration technology in accordance with the Washington
State Administrative Code (WAC) chapter 246-290.
2.3 REGULATORY
MANDATE
Recent updates
to the Washington Administrative Code have made filtration mandatory for most
water systems using surface water sources.
WAC 246-290-630 states that the water purveyor shall install and
properly operate water treatment processes to ensure at least 99.9 percent (3
log) removal and/or inactivation of Giardia
lamblia cysts and at least 99.99 percent (4 log) removal and/or
inactivation of viruses. In addition,
the WAC states that the purveyor shall treat all surface water sources using
one of the following filtration technologies unless another technology is
acceptable to the Department of Health (DOH):
Conventional, Direct, Diatomaceous Earth, or Slow Sand.
The WAC also
requires purveyors to conduct pilot studies for all proposed filtration
facilities, except where waived based on engineering justification acceptable
to the DOH. The WAC further states that
the purveyor shall ensure that the pilot study is (i) conducted to simulate
proposed full-scale design conditions and (ii) conducted over a time period
that will demonstrate the effectiveness and reliability of the proposed
treatment system during changes in seasonal and climatic conditions.
For slow sand
filters in particular, WAC 246-290-660 requires that the turbidity of the
finished water be less than or equal to 1.0 NTU (nephelometric turbidity unit)
in at least 95% of daily measurements made each calendar month, except where
waived based on health assessments acceptable to the DOH, and must never exceed
5.0 NTU.
WAC further
requires that drinking water meet the maximum contaminant levels (MCLs)
presented in 246-290-310, which include upper thresholds for twenty-five
inorganic substances. The MCL for total
trihalomethanes (TTHM) is 0.10 mg/L calculated on the basis of a running annual
average of quarterly samples. MCLs for
volatile organic compounds (VOCs) are to be met in accordance with the Code of
Federal Regulations, 40 CFR 141-61(a).
Secondary MCLs are specified for color, specific conductivity, and total
dissolved solids in WAC 246-290-310. If
slow sand filtration is selected, most of these contaminants should be below
mandated MCLs prior to treatment.
3.0 Slow SAND filtration tests
Pilot columns
were constructed in order to evaluate the effectiveness of slow rate filtration
on Domarie Creek surface water.
The City’s
chlorination system pump draws water directly from the raw water transmission
main supplying the reservoir.
Un-chlorinated water drawn from the downstream side of the chlorination
pump was diverted through the pilot columns for the duration of the project.
Four different
filter media were tested in the columns - crushed glass, Steilacoom sand,
Trinidad Pit sand, and Ellensburg sand.
The media were evaluated in parallel pilot columns. The Trinidad sand is
currently used in a slow sand filter at the City of Cashmere’s municipal
drinking water treatment plant, and the cities of Olga and Snow Creek use a
different gradation of the Steilacoom sand at their slow sand filtration
facilities.
City personnel
in conjunction with Gray & Osborne Inc. constructed and installed the pilot
columns, prepared the filter media, and monitored and maintained the pilot
project.
3.1 MATERIALS
AND APPARATUS
3.1.1 Pilot
Columns
A schematic
diagram of the pilot columns is provided in Figure 1, Appendix B. The columns were constructed of 15-inch
diameter SDR 35 PVC sewer pipe. Each
column contained 36 inches of filter medium underlain by several layers of
support gravels of increasing coarseness with depth. The succession of filter and support material is shown below:
36 inches Filter
Medium
6-inches Torpedo
Sand
3-inches Pea
Gravel
4-inches 7/8
Inch Gravel
6-inches 1 1/2 Inch Drain Rock
The support
media were lowered into the pilot columns in measured lifts and compacted. The filter media were then installed in
approximately 6-inch lifts and compacted after every lift.
After installing
the filter media, the columns were slowly backfilled with raw water. A 50
mg/L sodium hypochloride disinfectant solution was added to each column. This solution was drawn through the columns
until it completely filled the filter media and support gravels. The sodium hypochloride solution was allowed
to stand overnight in the columns before starting pilot project testing.
The flow rate to
each of the pilot columns was regulated by a rotometer-type direct flow
meter. As illustrated in Figure 1, the
rotometers were placed on the raw water supply to the columns, thereby
controlling the system. An overflow on
the distribution header feeding the rotometers provided a constant pressure head
to the rotometers. The filtered water
stream was discharged at atmospheric pressure above the top of the filter media
to avoid emergence of the media and to avoid siphoning. Flows of both raw and filtered water were
routed to free fall a short distance so that samples could be collected without
disturbing the system.
The columns were
located in a heated building located at the City’s reservoir site. Even though temperatures were maintained
above freezing, it is assumed that the temperature fluctuations experienced by
the pilot project were greater than would be experienced in a full-scale
facility.
3.1.2 Choice
of Filter Media
Filter media for
full scale facilities are typically selected based on size characteristics,
deliverable cost to site, and availability of adequate quantities for a
full-scale facility.[2] These same criteria were used in selecting
filter media for the pilot study.
The U.S. EPA’s
Office of Drinking Water recommends that slow sand filtration media “consist of
hard, durable grains free from clay, loam, dirt, and organic matter.”[3] The U.S. EPA Surface Water Treatment Guidance Manual and the Upper Mississippi
River Board of State Public Health & Environmental Managers Recommended Standards for Public Works (Ten
State Standards) include recommendations for slow sand filtration media
size characteristics. The
recommendations are that the media have a effective diameter or “d10”
(diameter which 10% by weight of the media is smaller than) between 0.35 mm and
0.15 mm, and a uniformity coefficient (U.C.) of 2.5 or less. The uniformity coefficient is the d60
(diameter which 60% by weight of the media is smaller than) divided by the d10.
|
Table 1 |
||||
|
Roslyn Slow Sand Filtration Pilot
Project |
||||
|
Filter
Media Description |
||||
|
Filter Media |
d10 |
U.C. |
Passing #200 Sieve |
Comments |
|
Crushed, recycled glass |
0.26 |
2.1 |
0.1% |
From Prairie City
Recycling, after washing. |
|
Steilacoom sand (8740) |
0.25 |
1.9 |
0.2% |
30 x 50 sand from Lone Star
Northwest Steilacoom plant. |
|
Trinidad Pit Sand |
0.25 |
2.5 |
1.5% |
From Dept. of Transportation. |
|
Ellensburg Masonry Sand |
0.20 |
2.4 |
0.4% |
From Ellensburg Cement
Products. |
The size
characteristics of all of the media used for this pilot project fall within the
EPA Guidance Manual and the Ten State Standards
recommendations. In addition to these
recommended characteristics, past experience has shown that the media should be
extremely clean, having less than 0.1% passing the number 200 screen (-200).
Crushed,
recycled glass and three sands were tested in the pilot study. A description of each filter medium is
provided in Table 1. Chart 1 shows the
gradation curves for comparison.
3.1.3 Filter
Media Washing
The filter media
and support gravels required additional washing in order to remove dirt
particles and to meet the desired cleanliness of less than 0.1% passing the
number 200 screen. Dirt in filter media
and support gravels has caused excessive turbidities in slow sand filters in
the past. The washing process has,
however, presented significant difficulties in past construction of full-scale
facilities.
For the pilot
project, washing was done in approximately 8 to 10-gallon batches of media or
gravel using a portable electric cement mixer in order to simulate the process
of using a cement truck on a full facility scale. The mixer was rotated while a stream of water maintained at
approximately 10 gallons per minute was introduced into the drum. A bucket was used to collect media or gravel
that washed out of the mixer during the cleaning operation. The washing apparatus was operated for
approximately 10 minutes per batch for the filter media and approximately 20
minutes per batch for the support gravels.
After washing, water was decanted from the mixer. Any media or gravel collected in the bucket
was returned to the mixer. The mixer
was operated for a short time in order to homogenize the media or gravel before
removal.
3.2 METHOD
OF OPERATION
The pilot
project was started on February 10, 1994 and operated until March 15,
1995. However, the crushed, recycled
glass pilot column was started on August 4, 1994.
The flow rate of raw water to the pilot columns was maintained at a
meter reading of 6.0 gallons per hour
(gph). This meter reading corresponded
to an actual measured flow of 4.0 to 4.7 gallons per hour and a hydraulic loading
rate to the filter media between 0.060 and 0.071 gpm/ft2. Typical loading rates for slow sand
filtration range between 0.040 and 0.100 gpm/ft2. Valves on the rotometers were observed and
adjusted as needed Monday through Friday of each week.
The proposed flow rate for a full sized facility is between 0.040
gpm/ft2 and 0.10 gpm/ft2. The pilot facility was operated at a flow typical for slow sand
filtration. During the pilot project,
raw water was fed continuously through the columns regardless of surface water
turbidity.
3.2.1 Filter
Media Cleaning During Operation
Both scraping and harrowing were tested as methods of cleaning the
filters when terminal headloss levels were reached. Scraping is the conventional method of cleaning slow sand filters
and basically removes the sand surface.
Scraping is done by draining the filter to a water level just below the
surface of the sand and removing the dirty filter-cake like material (often
termed the “Schmutzdecke”) along with the top 1/2 to 1 inch of sand. Harrowing is the process of turning over and
mixing the top few inches of sand while slowly backwashing the filter. Backwashing should be kept well below the
rate at which the bed becomes fluidized.
The water above the filter is decanted as the bed is turned over. Harrowing allows for a significant labor
savings over conventional scraping and also shortens the ripening period before
the filters can be placed back in use for potable water filtration.
3.2.2 Sample
Collection
Table 2 shows
the sample collection schedule for the pilot study. Samples indicated as having a “Daily” collection frequency were
sampled five days per week (Monday through Friday).
|
Table 2 |
||
|
Roslyn Slow Sand Pilot
Project Sampling Schedule |
||
|
|
||
|
Parameter |
Frequency |
Method |
|
Raw water turbidity |
Daily |
Grab samples with
portable turbidity meter (HACH 2100p) |
|
Filtered water turbidity |
Daily |
Grab samples with
portable turbidity meter (HACH 2100p) |
|
Headloss across filter |
Daily |
Differential reading on
piezometers |
|
Flowrate |
Daily |
Rotometer type direct
reading flow meter ( King 0-12 GPH ) |
|
Raw and finished water
temperature |
Daily |
Direct reading with
portable thermometer |
|
Total coliforms, fecal
coliforms |
Weekly |
Samples sent to Certified
lab |
|
pH |
Weekly |
Colorimetric |
|
Total Trihalomethanes |
Once |
Samples sent to Certified
lab |
|
Weather conditions &
notable events |
Daily |
Operator observations |
4.0 TEST PARAMETERS AND RESULTS
4.1 TURBIDITY
Raw and filtered
water turbidity samples were collected and measured once a day, five days per
week. Samples were analyzed using a
HACH 2100P portable turbidimeter. The
turbidimeter was calibrated on a regular basis to ensure accuracy.
Figures 2
through 6 in Appendix B show pilot project turbidity results. Figure 2 shows the raw water turbidity
determined from the City’s daily grab samples.
Figures 3-6 show the pilot column effluent turbidity results from the
four filter media.
Crushed glass
filter medium effluent turbidity appeared to reflect variations in raw water
turbidity. Higher effluent turbidity
was measured during periods of high raw water turbidity. During December, 1994, the glass filter
medium effluent exceeded 1.0 NTU (nephelometric turbidity unit) for more than
one day during the month, resulting in an exceedance of the WAC requirement of
turbidities less than or equal to 1.0 NTU in at least 95% of the measurements
made each month.
In general, the
Steilacoom and Trinidad Sands had higher effluent turbidity readings on days
experiencing high raw water turbidity than the Ellensburg Sand effluent. The Steilacoom Sand and the Trinidad Sand
both exceeded the WAC turbidity requirement (i.e. turbidities in at least 95%
of the measurements made each month less than or equal to 1.0 NTU) on one
occasion. The Ellensburg Sand met the
WAC turbidity requirement for the entire duration of the pilot project. It should be noted that all the turbidity
exceedances were associated with storm events.
The sand filters
produced relatively high effluent turbidities during start-up of the pilot
project. These high levels are normal
during start-up of a slow sand filter and are associated with material shedding
from the filter media and support gravels.
The Ellensburg Sand had a longer start-up phase with higher turbidity
levels than the other filter media tested.
This longer start-up phase was assumed to be due to wash-out of small
clay particles from the Ellensburg Sand since small clay particles were
observed during the initial washing process.
4.2 RATE
OF HEADLOSS DEVELOPMENT
The rate of
headloss development (pressure drop across the filter) over time is important
in determining the practicality of using slow sand filtration. When the filter units reach an unacceptably
high (terminal) headloss, they must be cleaned. This terminal headloss is a function of the full-scale facility
design. However, published values vary
between 1.0m and 1.5m (39 inches to 59 inches) according to the U.S. EPA Surface Water Treatment Guidance Manual
and are reported as high as to 2.2m (87 inches) according to the AWWA Manual of Design for Slow Sand Filtration. The AWWA also states that slow sand
filtration performance may be regarded as acceptable if filter runs of at least
one month can be achieved before headloss necessitates system cleaning.
Headloss across
the filter column was measured using piezometers located above the filter bed
and at the base of the filter support gravels.
Figures 7
through 10 in Appendix B compare the headloss versus volume filtered for the
four filter media. Dates of cleanings
are also shown on the Figures.
The AWWA
indicates in its Manual of Design for
Slow Sand Filters, that slow sand filtration performance may be regarded as
acceptable if filter runs of at least one month can be achieved before headloss
makes cleaning necessary. However, in
order for a slow rate filtration system to be practical for a city or utility,
longer filter runs are desirable.
During the pilot
project, all four media achieved a minimum of a one month interval before
headloss made cleaning necessary.
However, the cleaning interval varied greatly both over time and between
the four filter media. The Trinidad
Sand had the best performance with an average cleaning interval of 6
months. The crushed glass medium
required two cleanings over a six month test period. The Ellensburg Sand and the Steilacoom Sand each required three
cleanings over a thirteen month test period.
The rate of
headloss for the Steilacoom Sand, Ellensburg Sand, and the crushed glass
appeared to decrease significantly as the test progressed. This is in contrast to the Trinidad Sand
which showed a reduced rate of headloss during the second run.
The crushed
glass showed the most significant increase in the rate of headloss over the
first and second filter run. This may
be due to the method used for filter cleaning. After a filter run of over 3300 ft3, the filter was
harrowed. The subsequent filter run
volume was approximately 750 ft3.
Further filter runs would be required to test the effects of harrowing
as a cleaning method as compared to scraping and to test the effect of scraping
depth on filter run length.
4.3 BACTERIOLOGICAL
TESTING
Slow sand
filters utilize a combination of
biological and physical processes to remove contaminants. Bacteriological testing serves to
demonstrate that the filter beds have been adequately “ripened.” Ripening is the period initially after
start-up or after cleaning before the filter begins to provide adequate removal
of pathogens. Past research has shown
that these periods can vary from hours to days to weeks depending on raw water
conditions (such as temperature).
Bacteriological
testing requires documentation of both the source and finished water
quality. Bacteriological testing was
conducted for two groups of indicator organisms - total coliforms and fecal
coliforms. One raw water sample as well
as filtered water samples were collected weekly from each pilot column. The raw water samples from the City’s
transmission line varied from 2 to 300 total coliforms per 100 mL and 0 to 14 fecal
coliforms per 100 mL. The method of
analysis was Most Probable Number (MPN) as performed by Central Washington
University laboratory.
Tables 3 and 4
in Appendix B show the total coliform and fecal coliform test results for the
pilot study. The EPA Surface Water Treatment Guidance Manual
indicates that the removal capability of slow sand filtration is generally
appropriate for surface waters with total coliform bacteria concentrations of
less than 500 per 100 mL. This is only
a generalized capability parameter, actual applicability can be demonstration
through the use of a pilot study.
On October 31,
1994, the pilot columns were exposed to highly chlorinated water. This occurred when the transmission line was
shut-down for system maintenance but the positive pressure chlorination system
continued to operate. Water remaining
within the transmission line was continuously recirculated and
rechlorinated. The highly chlorinated
water was drawn through the pilot columns before the problem was identified and
corrected. Even though the volume and
the concentration of the chlorinated water drawn through the columns is not
known, it is assumed that the biological activity of the filter beds was
hindered.
The high
coliform counts measured in the pilot column effluent on 11/1/94 are attributed
to pilot column chlorination on October 31, 1994, coupled with interruption of
the flow in the transmission main and are therefore not shown on figures 11
through 14. The Ellensburg Sand and the
Steilacoom Sand pilot columns appear to have been impacted to a lesser degree
than the Trinidad Sand and crushed glass columns by exposure to the chlorinated
water.
In general, all
of the filter media appeared to have similar coliform removal
efficiencies. Figures 11 through 14
show the total coliform removal efficiencies (percent removal) for the four
filter media when raw water total coliform counts equaled or exceeded 25 per
100 mL. A MPN tube digestion method was
used to determine the total coliform levels and levels below 25 per 100 mL were
assumed not to be representative of bacterial removal.
4.4 TEMPERATURE
AND pH
Temperature and
pH are used to determine requirements for disinfection contact time for a
full-scale treatment facility and to evaluate potential influences on water
quality and corrosivity.
Temperature was
measured five days per week and pH was measured weekly. The PH of the Trinidad sand medium ranged
between 8.0 to 8.2. The pH was
approximately 7.4 for all other raw and treated water samples. Water temperatures varied from 5°C to 15°C.
4.5 DISINFECTION
BY-PRODUCTS
Trihalomethanes
are a group of chemicals known as disinfection by-products (DBP) since they are
primarily formed when specific organic chemicals (trihalomethane precursors)
naturally found in water are exposed to chlorine. The concentration of trihalomethanes is usually measured and
reported as total trihalomethanes (TTHM).
In addition, the
concentration of trihalomethane precursors can also be determined and is often
referred to as the measured maximum total trihalomethane formation potential
(MTTP). During MTTP analysis, water
samples are exposed to high levels of chlorine for an extended period of
time. It is assumed that all of the
trihalomethanes that can be formed under normal conditions are formed during
the extended laboratory incubation period.
Without additional treatment, slow sand filtration is not considered an
effective treatment method for removing trihalomethane precursors.
MTTP analysis
was performed on raw water and glass filter effluent samples collected during
the pilot plant operation.
Table 5
summarizes the sample analysis results for MTTP. A raw water sample and a crushed glass filter effluent sample
were collected on 10/21/95. Samples
were analyzed by the DOH Public Health Laboratories, Seattle, WA.
A comparison of
the MTTP concentrations from the two samples indicates that the difference lies
within the test method variability. The MTTP value is representative of the
maximum potential TTHM concentration.
Detailed results are provided in Appendix C.
Because WAC
regulations only require that MTTP be sampled on a quarterly basis, these
results do not necessarily indicate that this water is in violation of the MCL
of 100 mg/L. In addition, other pilot
tests have shown that, with certain process modifications, the removal of
precursor materials can be enhanced in slow sand filters.[4] The U.S. EPA is collecting data on the use
of alternate disinfectants or oxidants, including ozone, chlorine dioxide,
chloramines, and UV radiation. While a
combined use of disinfectants can effectively reduce TTHMs, these disinfectants
will produce other DBPs that are likely to require additional process
modifications in the future.[5]
|
|
||
|
Table 5 |
||
|
MTTP Disinfection
By-Product Results |
||
|
|
||
|
Collection Date |
Raw Water (mg/L) |
Crushed Glass (mg/L) |
|
10/21/94 |
162 |
212 |
4.6 METALS AND VOCs
One concern in
using the crushed, recycled glass as a filter medium was the unknown potential
for undesirable chemical and/or compounds to leach from the glass into the
drinking water. In order to evaluate
this concern, the effluent from the pilot column containing the crushed,
recycled glass was analyzed for metals and volatile organic compounds
(VOCs). The raw water source was also
analyzed for comparative purposes.
Results from the
raw water and glass pilot column effluent analyses for metals and VOCs are
included in the Appendix A. All of the
metals, inorganic compounds, and VOCs analyzed in both the raw water and the
glass pilot column effluent were below the Maximum Contamination Levels (MCLs).
4.7 OVERALL
EFFECTIVENESS OF FILTER MEDIA
A specific
objective of this pilot project was to evaluate the effectiveness of the
crushed, recycled glass as a slow rate filtration filter media. In addition, the effectiveness of the other
three sands was also evaluated.
|
Table 6 |
|||||
|
Filter Media Comparison |
|||||
|
|
|||||
|
Media |
No.
of Cleanings Required |
Filtered
Water Maximum Measured Turbidity (NTU) |
Met
WAC Turbidity Criteria: Yes/No (Exceedances) |
Average
Volume Filtered at 28 inches Headloss (ft3) |
Ratio
Largest to Smallest Filter Run Volume (ft3) |
|
Crushed
Glass |
2 in 7.5 weeks |
2.45 |
No (1) |
1,731 |
4.14 |
|
Steilacoom
Sand |
4 in 13 weeks |
2.57 |
No (1) |
1,665 |
4.21 |
|
Trinidad
Sand |
2 in 13 weeks |
2.09 |
No (1) |
3,148 |
1.13 |
|
Ellensburg
Sand |
4 in 13 weeks |
1.13 |
Yes |
1,733 |
4.40 |
Notes:
1) Test run time for the crushed glass column was approximately 7 1/2 months versus approximately 13 months for the three sand columns.
2) Turbidity maximum and WAC turbidity criteria do not include data obtained one day following transmission main maintenance and column chlorination.
3) Exceedances = the number of months in which the turbidity measurements were greater > 1 NTU in more than 5% of the measurement made each month.
A comparison of the
effectiveness of the filter media is presented above, in Table 6.
The crushed, recycled glass
and two of the three sands all violated the WAC requirements for turbidity
during one month of the pilot project.
The Ellensburg Sand never violated WAC requirements and appeared to
provide the maximum turbidity removal performance of all the media tested. The Trinidad Sand appeared to provide
minimum headloss development. The Trinidad Sand had the largest average volume
between cleanings and the lowest ratio of largest to smallest filter run volumes. Each of the filter media appeared to provide
similar bacteriological contaminant removal.
4.8 OPERATIONAL PROCEDURES AND FULL SCALE DESIGN CONSIDERATIONS
An important
feature of any pilot plant is to test operational methods proposed for use in
the full sized facility. For slow sand
filtration, the two fundamental operational procedures to test are flow rate
and proposed method of cleaning. The
pilot columns in this study were operated at a flow rate somewhat higher than
would be expected in the full sized facility.
In addition, the flow rate was held constant throughout the pilot plant
operation. The two methods of cleaning
evaluated were scraping and harrowing.
For filter
cleaning, both scraping and harrowing were found to be effective as a means of
cleaning the filters. However, column
headloss appeared to increase more rapidly after the filters were cleaned by
harrowing. It is not known if this is
the result of the cleaning procedure or variations in the raw water quality.
To allow for
harrowing, the final design should have the capability to backflush the slow
sand beds at a very low rate with filtered water, and contain piping for
decanting the water above the filter.
The filters should also be easily accessible to vehicles required to transport
large quantities of sand.
5.0 Conclusions and Recommendations
The pilot
project results suggest that slow rate filtration may be an effective treatment
process for the City of Roslyn raw water source with the addition of a roughing
filter or other method of pretreatment and/or the capability to divert raw
water during high turbidity events.
The crushed
glass medium satisfied the gradation characteristics set forth in the EPA Surface Water Treatment Rule Guidance Manual,
the Great Lakes Upper Mississippi River Board of State Public Health &
Environmental Managers Recommended
Standards for Water Works (Ten States Standards), and the AWWA Manual of Design for Slow Sand Filtration.
Maximum
contaminant levels for turbidity using the glass sand column were violated for
one month of the pilot project, but were otherwise in compliance. The removal of bacteriological contaminants
during the pilot study demonstrated that the glass filter media obtained the
activity level typically expected during slow rate filtration.
Caution must be
used when applying the conclusions of this pilot project to other water
systems. The effectiveness of a filter
medium and slow rate filtration treatment of drinking water are site
specific. Each water system must be
evaluated on a case-by-case basis.
The following recommendations
should be incorporated into the design of a full-scale facility:
·
A
full-scale facility should be divided into several filtration cells capable of
being independently operated, so that individual cells may be alternately taken
off line for cleaning and maintenance purposes.
·
A
full-scale facility should have the capability of being cleaned by either
scraping or harrowing. The facility
should have the capability of backwashing the individual filter cells with
filtered water and have adequate access for vehicles to transport of large
quantities of sand and for harrowing.
·
The
design of a full-scale facility should include an automatic control valve which
will divert flow away from the filter based on a high influent turbidity
set-point.
·
A
pre-treatment process should be considered in order to reduce the impact of
high raw water turbidity. The process
could consist of sedimentation basins or roughing filters.
·
A
full-scale facility should include covers to mitigate the potential for algal
growth in the filter beds.
It was observed
that the rate of headloss development increased over the length of the pilot
study for three of the four filter media.
It is not known if this trend was the result of changes in the pilot
columns cleaning methods or variations in raw water quality. Near the end of the pilot study, the rate of
headloss development approached the maximum acceptable limit. For this reason, it is recommended that the
pilot plant continue operation as long as possible. It is also recommended that testing be restricted to weekly
headloss measurements in order to minimize the expense of continuing the pilot
project.
It should be
noted that crushed glass typically has a lower density than sands and that as a
filter bed, it may fluidize at lower backflow rates than conventional
media. Therefore, caution should be
used during backfilling or backflushing for harrowing in order to avoid
fluidizing the bed and disrupting the structure of the filter beds and support
gravels.
In conclusion,
results from this pilot project indicate that the crushed recycled glass can
act as an effective filter medium for slow rate filtration of some raw water
sources. Further testing is warranted
for crushed glass to determine long term filter run lengths, maintenance techniques,
and particle characteristics of raw versus filtered water.
APPENDIX A
CHEMICAL
ANALYSES


APPENDIX B
·
TURBIDITIES
·
HEAD LOSSES
·
COLIFORM REMOVAL EFFICIENCIES
APPENDIX C
TRIHALOMETHANES


[1] Cleasby, John L. “Source Water Quality and Pretreatment Options for Slow Sand Filters,” in Slow Sand Filtration, American Society of Civil Engineers, 1991.
[2] Slow sand filters occupy more space than conventional rapid filters, and typically require tens of thousands of cubic feet of sand.
[3] U.S. EPA, Office of Drinking Water. Manual of Small Public Water Supply Systems, C. K. Smoley, 1992.
[4] Collins, M. R., and T. T. Eighmy. Modifications to the Slow Sand Filtration Process for Improved Removals of Trihalomethane Precursors. American Water Works Research Foundation and American Water Works Association, Denver, 1989.
[5] Clark, Robert M., ed. Strategies and Technologies for Meeting SDWA Requirements. Technomic Publishing Co., Inc., Lancaster, 1993.